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High Performance Polymers
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Article

Benzophenone-Type Unsymmetrical Substituted Aromatic Diamines and Organosoluble Polyimides Therefrom

Alexander L. Rusanov1, Ludmila G. Komarova1*, Marina P. Prigozhina1, Roman S. Begunov2, and Yulia S. Yakovleva2

1 A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow Russia
2 Yaroslavl State University, Yaroslavl, Russia

* To whom correspondence should be addressed.


  Abstract

Benzophenone-type unsymmetrical substituted aromatic diamines of general formula

were prepared starting with p-nitrobenzoyl chloride and substituted benzenes. Interaction of the diamines obtained with aromatic tetracarboxylic acids dianhydrides under the conditions of high-temperature solution polycyclocondensation in m-cresol led to the formation of new high molecular weight organosoluble polyimides.

Key Words: Polyimides (PIs), organosoluble, aromatic diamines, aromatic tetracarboxylic acids dianhydrides, high temperature solution polycyclocondensation

First published on December 23, 2008
High Performance Polymers 2008, doi:10.1177/0954008308099187
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