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High Performance Polymers
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The Effect of Conformational Rigidity on Several Physical Properties of Polymers

I A Ronova

S S A Pavlova

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813 Russia

The phenomenological dependences of several physical properties such as the softening temperature, friction coefficient, elasticity modulus, fire-resistance parameters and quantum luminescence yield on the conformational rigidity of a polymeric chain are revealed for polyheteroarylenes. The contribution of the conformational rigidity of a polymer chain to the physical properties of this class of polymers is shown to be significant. It should be taken into account in estimation of the above-mentioned properties together with the contribution of intermolecular interactions.

High Performance Polymers, Vol. 10, No. 3, 309-329 (1998)
DOI: 10.1088/0954-0083/10/3/007
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