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High Performance Polymers
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New Parabanate Products by 1, 3-Dipolar Cycloaddition Reaction (‘Criss-Cross’ Cycloaddition)

Adrian A Caraculacu

Elena Scortanu

Georgeta Caraculacu

Institute of Macromolecular Chemistry ‘Petru Poni’, Aleea Grigore Ghica Voda, No 41 A, 6600 Iasi, Romania

New parabanate products containing 1, 3, 5, 7-tetraazabicyclo[3, 3, 0]octane-2, 6-dione are described. The synthesis of {alpha}{omega}-diisocyanato-telechelics starting from two diisocyanates having a preformed parabanic unit using a [3+2] dipolar cycloaddition reaction was studied. The obtained products were characterized by IR spectroscopy, elemental and thermogravimetric analyses and solubility tests. The proposed structure was confirmed by analytical data.

High Performance Polymers, Vol. 11, No. 4, 477-482 (1999)
DOI: 10.1088/0954-0083/11/4/311
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