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High Performance Polymers
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Aromatic Polyethers based on Meta-activated Dinitrocompounds

Alexander L. Rusanov

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Ludmila G. Komarova

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia, komarova{at}ineos.ac.ru

Aromatic polyethers containing phenyl sulfone side groups were prepared using aromatic nucleophilic nitrosubstitution reaction. As starting compounds TNT-derived 3,5-dinitrodiphenyl sulfone and 4,4'-bis-[(3-nitro-5-phenylsulfonyl)phenylsulfonyl]diphenyl sulfone containing functional nitro groups activated with electron-withdrawing phenylsulfone meta-substituents were used. Polymers obtained are soluble in wide range of organic solvents and demonstrate large ‘windows’ between their softening and degradation temperatures.

Key Words: aromatic polyethers • organosoluble • meta-activated dinitrocompounds • bis-phenols • aromatic nucleophilic nitrodisplacement reactions

This version was published on October 1, 2009

High Performance Polymers, Vol. 21, No. 5, 535-547 (2009)
DOI: 10.1177/0954008309339220
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